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Creators/Authors contains: "Jha, Soocheta"

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  1. Free, publicly-accessible full text available August 22, 2026
  2. Diaryliodonium-amine complexes are proposed as key intermediates in C–N coupling reactions. The Lewis basicity of synthetically relevant amines are quantified on the Legault iodonium Lewis acidity scale. 
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    Free, publicly-accessible full text available July 31, 2026
  3. Abstract We describe the development of a C–O coupling reaction between aryl(2,4,6-trimethoxyphenyl)iodonium salts and aliphatic alcohols under weak base conditions. The scope of the reaction is presented, with 16 examples ranging in yield from moderate to high (54–96%). The limitations of the reaction are also presented. Mechanistic experiments reveal a complex network of reactions that include side reactions that generate arynes and oxidize the alcohol nucleophile. 
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